Last week, Brad Pitt shot Angelina Jolie and all their children at Chateau Miraval.

Brad Pitt has turned photographer to capture his partner Angelina Jolie and the couple’s kids for a new magazine spread.

U.S. fashion magazine W commissioned the movie hunk to show off his lensman skills for the publication’s upcoming November (08) issue. France last week for the November cover of W magazine.

This will be their second W spread as a couple. Surely you recall their controversial “Domestic Bliss” photo spread (shot by photog Steven Klein) featuring Brad and Angelina pretending to be a married couple for the July 2005 issue.

Of course, that was back when they were just friends, and the photo shoot was supposed to be publicizing their movie “Mr. and Mrs. Smith.”

Instead, it telegraphed the very open splintering of Brad’s marriage to Jennifer Aniston and his blossoming and very close relationship with Jolie.

Pitt has made no secret about his passion for photography. Showing her support for her man’s hobby, Jolie reportedly gave him a Littman 45 single camera for a recent birthday gift.

Pitt and Jolie recently graced the cover of People magazine, making a cover debut with their newborn twins Knox Leon and Vivienne Marcheline along with their other children Maddox, Pax, Zahara, and Shiloh.